Study of solvent-based carbon capture for cargo ships through process modelling and simulation

摘要

Controlling anthropogenic CO2 emission is crucial to mitigate global warming. Marine CO2 emissions accounts for around 3% of the total CO2 emission worldwide and grows rapidly with increasing demand for passenger and cargo transport. The International Maritime Organization (IMO) has adopted mandatory measures to reduce greenhouse gases (GHGs) emissions from international shipping. This study aims to explore how to apply solvent-based post-combustion carbon capture (PCC) process to capture CO2 from the energy system in a typical cargo ship and to evaluate the cost degrees of different integration options through simulation-based techno-economic assessments. The selected reference cargo ship has a propulsion system consisting of two four-stroke reciprocating engines at a total power of 17 MW. The study first addressed the challenge on model development of the marine diesel engines and then developed the model of the ship energy system. The limitations of implementing onboard carbon capture were discussed. Two integration options between the ship energy system and the carbon capture process were simulated to analyse the thermal performance of the integrated system and to estimate equipment size of the carbon capture process. It was found that the carbon capture level could only reach 73% when the existing ship energy system is integrated with the PCC process due to limited heat and electricity supply for CCS. The cost of CO2 captured is around 77.50 €/ton CO2. With installation of an additional gas turbine to provide extra energy utilities to the capture plant, the carbon capture level could reach 90% whilst the cost of CO2 captured is around 163.07 €/ton CO2, mainly because of 21.41% more fuel consumption for the additional diesel gas turbine. This is the first systematical study in applying solvent-based carbon capture for ships, which will inspire other researchers in this area.